Sodium silicate

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Expantrol proprietary sodium silicate suspended in an about 6.5 mm thick layer of red rubber, type 3M FS195, inserted into a metal pipe, then heated, to demonstrate hard char intumescence, strong enough to shut a melting plastic pipe.

Sodium silicate is the common name for a compound sodium metasilicate, Na2SiO3, also known as water glass or liquid glass. It is available in aqueous solution and in solid form and is used in cements, passive fire protection, refractories, textile and lumber processing, and automobiles. Sodium carbonate and silicon dioxide react when molten to form sodium silicate and carbon dioxide:

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